| Organic Chemistry by Solomons, Fryhle and Synder 11th and 12th editions |
| Chapter 13 Conjugated unsaturated systems |
Active-learning Questions (completed individually)
-
What is a conjugated
unsaturated system? In other words, what is meant by the term conjugated unsaturated? Provide 3 point-form statements.
- Use the molecular
orbital and the resonance theories
to describe the structure of the allyl
radical. For each theory provide a series of structure drawings, as well as
an illustration of the overall structure of the radical. Label the drawings
with arrows to identify the important components, and use short point-form
statements to describe what is happening in each drawing.
- According to the molecular orbital approach, why
is the allyl radical stable (2 point-form
statements)? According to the resonance theory, why is the allyl radical
stable (2 point-form statements)?
- What happens when a substance
absorbs ultraviolet or visible light? Provide a diagram in your description. Do
not forget to provide the relationship between the energy gap and the
wavelength of light absorbed. Maximum 2 point-form statements.
- What does the
spectrophotometer measure and what does it produce? Do not describe the process
occurring within the instrument itself. Maximum 2 point-form statements.
- Draw and describe the absorption
spectrum and its three characteristics. Maximum 4 point-form statements.
Portfolio Questions (completed individually)- Draw structures and provide
the names of A, B and C in Figure 4
below. Show your work.
- Using Figure 5 below:
- Identify the spectrum of a conjugated unsaturated
molecule. Explain your choice.
- Identify the spectrum of an unconjugated
unsaturated molecule. Explain your
choice.
- Which spectrum is that of a colored
compound? What is the color of the compound? Explain.
|
| Section | Subject |
| 13.1 | Introduction |
| 13.2 | The stability of the
allyl radical (omit Figure 13.1) |
| 13.3 | The allyl cation (omit Figure 13.2) |
| 13.4 | Resonance theory revisited |
| 13.5 | Alkadienes and
polyunsaturated hydrocarbons |
| 13.6 | 1,3-butadiene:
Electron delocalization (omit 13.6C) |
| 13.7 | The stability of
conjugated dienes |
| 13.8 | Ultraviolet-Visible
spectroscopy |