| Chapter 4 Nomenclature and conformations of alkanes and cycloalkanes | |||
| 12th edition Solomons, Fryhle and Snyder Organic Chemistry | 11th edition Solomons, Fryhle and Snyde Organic Chemistry | ||
| Problems | Section | Subject | Problems |
| 4.1 | Introduction of alkanes and cycloalkanes | ||
| Practice problem 4.1 (it is enough to be able to draw 5 constitutional isomers) | 4.2 | Shapes of alkanes | Practice problem 4.1 |
| Solved problems 4.1, 4.2 Practice problems 4.2, 4.3, 4.4, 4.6, 4.7 | 4.3 | How to name alkanes, alkyl halides and alcohols: The IUPAC system | Solved problems 4.1, 4.2 Practice problems 4.2, 4.3, 4.4, 4.6, 4.7 |
| Solved problem 4.3 Practice problems 4.8, 4.9 | 4.4 | How to name cycloalkanes | Solved problem 4.3 Practice problems 4.8, 4.9 |
| Solved problem 4.4 Practice problems 4.10, 4.11 | 4.5 | How to name alkenes and cycloalkenes | Solved problem 4.4 Practice problems 4.10, 4.11 |
| Practice problem 4.12 | 4.6 | How to name alkynes | Practice problem 4.12 |
| Required reading | 4.7 | Physical properties of alkanes and cycloalkanes | Required reading |
| These sections are part of chapter 4c on the conformations of ethane and cyclohexane, and are not evaluated on test 1. | 4.8 | Sigma bonds and bond rotation | These sections are part of chapter 4c on the conformations of ethane and cyclohexane, and are not evaluated on test 1. |
| 4.11 | Conformations of cyclohexane: The chair and the boat | ||
| 4.12 | Substituted cyclohexanes: Axial and equatorial hydrogen groups | ||
| 4.13 | Disubstituted cycloalkanes: Cis-trans isomerism | ||
| Solved problem 4.5, 4.6 Practice problems 4.15, 4.16, 4.17, 4.18 This section and these questions are part of chapter 4c on the conformations of ethane and cyclohexane, and are not evaluated on test 1. | 4.13A | Cis-trans isomerism and conformational structures of cyclohexane | Solved problem 4.5, 4.6 Practice problems 4.15, 4.16, 4.17, 4.18 This section and these questions are part of chapter 4c on the conformations of ethane and cyclohexane, and are not evaluated on test 1. |
| 4.14 | Bicyclic and polycyclic alkanes | ||
| 4.15 | Chemical reactions of alkanes | ||
| Solved problem 4.7 Practice problem 4.19 | 4.16 | Synthesis of alkanes and cycloalkanes | Solved problem 4.7 Practice problem 4.19 |
| Practice problems 4.20, 4.22 | 4.17 | How to gain structural information from moleculare formulas and the index of hydrogen deficiency (degree of unsaturation) | Practice problems 4.20, 4.22 |
| Chapter 12 Alcohols from carbonyl compounds. Oxidation-reduction and organometallic compounds | |||
| Problems | Section | Subject | Problems |
| p 547 | 12.5 | Organometallic compounds | p 556 |
| p 548 | 12.6 | Preparation of organolithium and organomagnesium compounds | p 557 |
| p 549 Solved problem 12.2 Practice problems 12.4, 12.5B | 12.7A | Reactions of organolithium and organomagnesium compounds (omit 12.7B and 12.7C) | p 558 Solved problem 12.3 Practice problems 12.6, 12.7B |
| p 954 21.6 E Gilman reagent-mediated couplings (Chapter 21) Practice Problem 21.11 | The Corey-Posner, Whitesides-House reaction: Use of lithium dialkyl cuprates (Gilman reagents) in coupling reactions | Special topic G.3, p G-7 (this section is located between chapters 21 and 22) Problem G.10 | |
| Chapter 4 end of chapter problems | Chapter 4 end of chapter problems | ||
| 4.23, 4.24*, 4.26, 4.27, 4.28, 4.29, 4.32, 4.39, 4.46 | 4.23, 4.24*, 4.26, 4.27, 4.28, 4.29, 4.39 | ||
| *Answer for 4.24 G: 5,6-dimethyl-2-heptene | *Answer for 4.24 G: 5,6-dimethyl-2-heptene | ||
| 4.37 and 4.43. These problems are to be completed after studying chapter 4c on the conformations of ethane and cyclohexane. They are not evaluated on test 1. | 4.37 and 4.43. These problems are to be completed after studying chapter 4c on the conformations of ethane and cyclohexane. They are not evaluated on test 1. | ||