| Chapter 6 Nucleophilic Reactions | Chapter 6 Ionic Reactions | ||
| 12th edition Solomons, Fryhle and Snyder Organic Chemistry | 11th edition Solomons, Fryhle and Snyde Organic Chemistry | ||
| Problems | Section | Subject | Problems |
| Required reading Practice problem 6.1, 6.2 | 6.1 | Alkyl halides | Required reading Practice problem 6.1, 6.2 |
| Solved problem 6.1 | 6.2 | Nucleophilic substitution reactions | Solved problem 6.1 |
| Solved problem 6.2 Practice problem 6.3 | 6.3 | Nucleophiles | Solved problem 6.2 Practice problem 6.3 |
| 6.4 | Leaving groups | ||
| 6.5 | Kinetics of a nucleophilic substitution reaction: An SN2 reaction | ||
| 6.6 | A mechanism for the SN2 reaction Mechanism: Mechanism for the SN2 reaction (p247) | ||
| Solved problem 6.3 Practice problem 6.5 | 6.8 | The stereochemistry of SN2 reactions Mechanism: The stereochemistry of an SN2 reaction (p253) | Solved problem 6.3 Practice problem 6.5 |
| 6.9 | The reaction of tert-butyl chloride with hydroxide ion: An SN1 reaction | ||
| 6.10 | A mechanism for the SN1 reaction Mechanism: Mechanism for the SN1 reaction (p255) | ||
| Solved problem 6.4 Practice problem 6.7 | 6.11 | Carbocations | Solved problem 6.4 Practice problem 6.7 |
| Solved problem 6.5 Practice problems 6.8, 6.9 | 6.12 | The stereochemistry of SN1 reactions Mechanism: The stereochemistry of an SN1 reaction (p259) | Solved problem 6.5 Practice problems 6.8, 6.9 |
| Solved problems 6.6, 6.7 Practice problems 6.10, 6.14, 6.15, 6.17 | 6.13 | Factors affecting the rates of SN1 and SN2 reactions | Solved problems 6.6, 6.7 Practice problems 6.10, 6.14, 6.15, 6.17, 6.18 |
| Practice problem 6.19 | 6.14 | Organic synthesis: Functional group transformations using SN2 reactions | Practice problem 6.19 |
| Elimination reactions - see Chapter 7 of the 12th edition | 6.15 | Elimination reactions of alkyl halides | |
| 6.16 | The E2 reaction Mechanism: Mechanism for the E2 reaction (p277) | ||
| 6.17 | The E1 reaction Mechanism: Mechanism for the E1 reaction (p279) | ||
| 6.18 | How to determine whether substitution or elimination is favored. Read this section only. You must use the summary table (Summary of SN1, SN2, E1 and E2 reactions) that I gave you to determine the products that will form when a haloalkane reacts with a base. Solved problem 6.8 on pages 282 and 283 is very important. Use the summary table I gave you to determine that products of each reaction. The answers on in the solutions manual may differ from those that you get by following my summary table. This is normal. | ||
| 6.19 | Overall summary | Solved problem 6.8 | |
| End of chapter problems | End of chapter problems | ||
| 6.23, 6.24, 6.25 (omit D) 6.26, 6.27 | 6.20, 6.23, 6.24, 6.25 omit D, E, 6.27, 6.28 | ||
| 6.29 To determine the products of the reaction follow the summary table I gave you. Answer for 6.29 F: SN1 major and E1 minor. Answer for 6.29 H: SN2 only product. | |||
| 6.30 |