| Chapter 8. Alkenes and Alkynes II: Addition Reactions | ||
| 12th edition Solomons, Fryhle and Snyder Organic Chemistry | ||
| Problems | Section | Subject |
| 8.1 | Addition reactions of alkenes | |
| Practice problem 8.1, 8.2 | 8.2 | Electrophilic addition of hydrogen halides to alkenes: Mechanism and Markovnikov's rule Mechanism: Addition of a hydrogen halide to an alkene Mechanism: Addition of HBr to 2-methylpropene |
| Chapter 10. Radical reactions | ||
| Problems | Section | Subject |
| 10.10 | Radical addition of alkenes: The anti-Markovnikov addition of hydrogen bromide | |
| Chapter 8. Alkenes and Alkynes II: Addition Reactions | ||
| Problems | Section | Subject |
| Solved problem 8.1 Practice problem 8.4, 8.5, 8.7, 8.8 | 8.4 | Addition of water to alkenes: Acid-catalyzed hydration Mechanism: Acid-catalyzed hydration of an alkene |
| 8.6 | Alcohols from alkenes through hydroboration-oxidation: Anti-Markovnikov syn addition | |
| 8.7 | Hydroboration: Synthesis of alkylboranes | |
| Solved problem 8.3 Practice problem 8.13 | 8.8 | Oxidation and hydrolysis of alkylboranes |
| 8.11 | Electrophilic addition of bromine and chlorine to alkenes Mechanism: Addition of bromine to an alkene | |
| End of chapter problems | ||
| 8.26 Do only A, B, E, F, H, M | ||
| 8.27 | ||
| 8.28 Omit B and E. | ||
| 8.29 G answer: at low T the products are:, CH2=C(CH3)2 (E2 major) et CH3CH2C≡CC(CH3)3 (SN1 minor); at high T the product is CH2=C(CH3)2 (E2 only) | ||
| 8.30 Omit J and KK.,, | ||
| 8.31 Omit D | ||
| 8.32 Omit C and D | ||
| 8.33 Omit C | ||